Iidentification of Dye class on fibres
Dye class identification is very important test to select a relevant
dye for particular fibre or fabric. All kinds dyes are not suitable for all
textile fibres. For example Reactive dyes are confidently identified for
natural cellulose fibres, because it is possible to associate the reactive dyes
structure with the cellulose fibre structure. If the fibre material is
unknown, Fibre identification should be carried out first.
Dye class identification for various fibres |
The most well-known dye class identification systems on fibres
are:
I. Krefeld method:
a) For cellulose fibres (cotton, silk, jute etc): dissolve fibre
sample in suitable solvent, sulphur test (for sulphur-based dyes), blind vat (oxidation
and cationic dyes), stripping and staining reactions (for mordant, acid, direct
and diazo dyes), dimethyl formamide test (for reactive dyes), glacial acetic
acid test (for vat, naphthol and phthalocyanine dyes).
b) For animal fibres (wool): paraffin test, blind vat and
reoxidation (for vat and naphthol dyes), detection of metals (metal complex and
chrome dyes), cold glacial acetic acid (cationic dyes), suitable solvent
(reactive, acid and direct dyes).
c) For synthetic fibres: a caprolactam melt is prepared or
stripping by means of glacial acetic acid carried out. The melt and the solution
are mixed with ether and processed further. Dye classes which can be identified
are disperse, metal complex, chrome, acid, cationic and naphthol dyes.
II. Reutlinger method:
a) For cellulosic fibres: water, wash, paraffin, pyridine, glacial
acetic acid, hydrogen sulphide, chlorine, benzene tests and blind vat.
b) For animal fibres: water, wash, paraffin, glacial ace tic
acid, ammonia, pyridine, benzene tests and blind vat.
c) For synthetic fibres: Acetate, Polyamide and Acrylic
dyes.
III. In accordance with the AATCC guidelines for cellulosic,
animal and synthetic fibres.
Dye classification:
A distinction is made between the following methods of
classification:
I. Scientific classification of dyes based on their chemical
structure, e.g. anthraquinone, azo dyes, etc.
II. Technical classification of dyes based on their dyeing
properties, e.g. direct, acid, wool dyes, etc.
III. Commercial classification of dyes based on various
aspects according to the manufacturer, e.g. according to fastness properties
such as Sirius Light, Indanthren, etc. or according to the method of dyeing under
collective names, e.g. Remazol = reactive dyes (Dystar), Palanil = disperse
dyes (BASF), etc.
Wish you good luck-------------------------------------------
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