Showing posts with label Direct dyes. Show all posts
Showing posts with label Direct dyes. Show all posts

5/20/13

Dyeing methods of Direct dyes

Direct dye is populae and conventional dye. There are some popular dyeing method of direct dyeing with suitable dyeing machine those are describeb bellow:
I. Batch method: With batch dyeing, the dyeing method to be selected in each case depends on the type of dyeing equipment (loading system, winch vat, jig, paddle or jet), the nature of the material to be dyed, as well as the solubility and the affinity of the dye. Before the actual dyeing process, the material is pre-treated with a wetting agent. The dye is mixed into a paste with some warm water, and is then diluted with more water, boiled up, filtered, and then added to the dyebath.

Whilst the bath, with the fabric, heats up to the optimum temperature (usually 80–90°C), the electrolyte is added, gradually if necessary. Dyeing takes 30–60 minutes. After the dyebath has been run off, the dyed material is briefly rinsed with cold water and, in general, subjected to after-treatment. The dyeing process is divided into 3 phases: a) uptake (adsorption) through substantivity; b) penetration of the dye into the fibre (diffusion); c) bonding to the fibre (immobilisation) through van der Waals interactions. Assurance of level take-up through progessive addition of salt, temperature control, sufficiently long dyeing time, and use of levelling agents.

II. High-temperature dyeing method:
With suitable dyes, one can work in a closed system at temperatures over 100°C (up to approx. 130°). Due to the rapid diffusion rate, particularly level dyeings are achieved with short dyeing times, even with fabric with difficult dye penetration. After the high-temperature phase, the dyebath is cooled down to 80–90°C, with dye pick-up continuing, and the result is the same depth of colour as in the normal dyeing method at 80–90°C.

III. Continuous and semi-continuous method: With these so-called pad methods, the dyeing material, mostly in the form of woven fabric, is first of all steeped in a concentrated dye solution, passed full-width through a trough filled with the dye solution, and subsequently the excess liquor is removed between the rubber rollers. With high fabric speed, temperatures as low as possible (30–40°C for light shades, 60–80°C for medium to dark shades), and with the minimum amount of pad liquor, the situation can be avoided where the dye already picks up substantively in the padding process. Distinction may be made between the following methods:

1. Pad-jig method: Pad, salt bath develop on jig or winch vat.

2. Pad-roll method: Pad, heat up in an IR zone, roll up and rotate in a dwell chamber for a considerable time under fixation temperature/moisture conditions.

3. Pad-salt method: Pad, pass through salt solution at boil in continuous piece-dyeing machine (light shades only; for darker shades an intermediate steam process is necessary).

4. Pad-steam method: Pad, continuous steam, optional final salt bath.

5. HT-steam method: Pad, HT-steam.
After-treatment: The wetfastness properties of direct dyeings are not adequate for the demands of everyday use, particularly in medium and deep shades.


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Direct dyes

Direct dyes are very conventional dyes. It is not used any more for industrial dyeing. Direct dye is one kind of anionic dye and having substantively for all types of cellulosic fibre like cotton, jute, hemp. They have strong affinity to the fibre which can be applied directly on the fibre surface and do not need any assistance.

Direct dye Also known as direct, substantive, benzidine or salt dyes. Group classification for dye which exhaust substantively on cellulosic fibres, cotton, viscose, cupro and high wet modulus fibres, especially in the presence of salt. Chemically they are polyazo or sulphonated disazo dye.It contains sulphonic acid group that’s why is has good solubility in water. The dye molecule contains a complex bond metal atom that’s why they have high light fastness properties. The color fastness is poor but it is easy to improve by dyeing after treatment with metal salts (Õ Aftercoppering dyes).

Benefit of Direct dye:

Direct dyes represent the main class of dyes for cellulosic fibres in terms of usage:
- Specially selected direct dyes are available for streaky dyeing viscose qualities.
- They are simple to apply.
- Economical or cost effective than any other dyes.
- It has generally good leveling properties
- A wide range of color variation and shade.
- Special types contain better wet fastness. It is possible to couple with readily soluble diazo compound by after treatment.
-Direct dyeing on cellulosic fibres exhibit considerable differences in colour fastness to light which ranges between 1 and 7–8.

Different direct dyes can therefore be used for articles which are only required to have low light fastness as well as goods with high light fastness. In general, direct dyes have poor wet fastness properties and dyeing must be after treated to improve their serviceability.

Properties of direct dye:
- Direct dye has sodium salt of sulphonic acid or carboxylic acid group. So it easily dissolve in water.
- Cheap comparative
- It has strong affinity to cellulose fibre. It is possible to dye protein fibre.
- Easily disperse in water and diffusible in to fibre.
- Wash fastness is not good. The range vary from 2 to 3
- It is possible to use in neutral and alkaline medium
- The dye is common in the practical point of view.
- The tin tropical power of this dye is very good.

Some trade and brand name of direct dyes
Benzo, Benzoform       - F.Bayer (Germany)
Coprantine                  - Ciba-geigy (Switzerland)
Solphenyl                    - Ciba-geigy (Switzerland)
Chlorazol Durazol        - Impartial Chemical Industry (ICI)
Solar                          - Sandoz A.G (Switzerland)

There are some related posts to get deep knowledge of direct dye:

# Classification of Direct dye
# How to dye with direct dyes
# Dyeing aftertreatment of direct dye
# Chemistry of dyeing related to direct dye
# Dyeing auxiliaries required for direct dye

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